Extrait:The deal will give better access for UK whisky and cars to the Indian market.
Last year trade between the UK and India totalled £41bn and was already forecast to grow, but the government said the deal would boost that trade by an additional £25.5bn a year by 2040.
Mr Reynolds met his Indian counterpart Piyush Goyal in London last week to put the final touches on the deal.
Once it comes into force, which could take up to a year, UK consumers were likely to benefit from the reduction in tariffs on goods coming into the country from India, the Department for Business said.
As well as clothing, that will include some Indian foodstuffs, such as frozen prawns.
The government also emphasised the benefit to economic growth and job creation from UK firms expanding exports to India.
Gin and whisky tariffs will be halved to 75%, with further reductions taking effect in later years.
Import taxes on cars will fall to 10% as will levies on aerospace, electricals and some UK food products.
India is forecast to become the worlds third-largest economy in a few years.
US President Donald Trumps tariff campaign has focused minds in other countries on how to respond, and increased the impetus to strike trade deals.
The UK is also a high priority trading partner for Indian Prime Minister Narendra Modis government, which has an ambitious target to grow exports by $1 trillion by 2030.
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